专利名称：4 buromo 3,5,6 torihuruorohutaru and the manufacturing method and manufacturing
method null of 3 buromo 2,4,5 trifluoro
发明人：NIIZEKI SHUSUKE，新夕 秀典,IMAI YASUSHI，今井 靖志,YOSHIDA MASAHIKO，吉田 昌
彦,SASAKI MASANORI，佐々木 正典,MYATA
KAZUYOSHI，宮田 一芳,SHIBABUCHI HIROSHI,buchi
芝淵 弘
申请号：JP特願平2-80686
申请日：19900330
公开号：JP第2893546号B2
公开日：
19990524
专利内容由知识产权出版社提供
摘要：NEW MATERIAL:4-Bromo-3,5,6-trifluorophthalonitrile expressed by formula I and 4-bromo-3,5,6-trifluorophthalic acid expressed by formula II. USE:An intermediate raw material for functional polymer materials, medicines, agricultural chemicals and liquid crystal materials, etc. PREPARATION:Tetrafluorophthalonitrile is reacted with a metal bromide in an aprotic polar organic solvent, preferably sulfolane or N, N-dimethylformamide to stop the reaction when the rate of reaction attains 20-50%, preferably 25-45%. Thereby, the objective compound expressed by formula I is efficiently obtained. The resultant compound expressed by formula I is hydrolyzed in an aqueous soluti
on of an inorganic acid (preferably sulfuric acid) to provided the compound expressed by formula II. Furthermore, the compound expressed by formula II is decarboxylated to readily afford 3- bromo-2,4,5-trifluorobenzoic acid.
申请人：NIPPON KAABAIDO KOGYO KK，日本カーバイド工業株式会社地址：東京都千代田区丸の内3丁目3番1号
国籍：JP
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